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Protein rossmann
F, g Rossmann/Rossmann-like and HTH domain proteins that were enriched in 2C and PTex RBPome data. Supersecondary structure of protein • Intermediate between secondary and tertiary structures of protein. • Also called motifs. • Typically composed of two secondary structures and a turn or loop. • Simple combinations of few secondary structure elements with a specific geometric arrangement – occur frequently in protein structures. The Rossmann fold [1,2] is an ancient and structurally diverse fold initially discovered in a wide range of nucleotide-binding proteins that bind diphosphate-containing cofactors such as NAD(H). The Rossmann fold is characterized as a repeat of the βαβαβ structure which has twofold symmetry and binds to a dinucleotide such as nicotinamide adenine dinucleotide (NAD) or flavin adenine dinucleotide (FAD) to catalyze multiple types of reactions (Shin & Kihara, 1958). It is composed of a series of alternating beta strand (β) and alpha helical (α) segments wherein the β-strands are hydrogen bonded forming a β-sheet. The initial beta-alpha-beta (βαβ) fold is the most conserved segment of Rossmann folds. The classical Rossmann fold, also known as a doubly-wound three layer a/b-sandwich, consists of two-units (321456 topology) that form a single parallel sheet flanked by alpha-helices on both sides and contain a characteristic crossover between strands 3 and 4.
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